CARBONIZATION OF BANTEN COAL BY ADDING WATER STEAM; CHANGES ON CARBON FUNCTIONAL GROUPS AND PORE CHARACTERISTICS
DOI:
https://doi.org/10.30556/imj.Vol17.No3.2014.320Keywords:
carbonization, upgrading process and maturation analysesAbstract
Experimental research and a fundamental study of carbonization of coal have been done by adding steam. The coal sample used in this study was obtained from Bayah, Banten, where the coal was mined by a small-scale underground mining. The study was carried out on a laboratory-scale of adjustable tube furnace reactor. The processes could give carbonized coal with a high calorific value (about 7,600 kcal/kg) and a high fixed carbon content (about 87 wt%). Specific surface area of carbonized products was also interesting as having for 160.5 m2/g. Specific surface area and pore distribution determined by BET techniques and also scanning electron microscope analyses were used to test for the pore and physical properties in the coal. In addition, changes in carbon functional groups and their properties were determined by Fourier Transform Infrared Spectroscopy and Raman Spectroscopy analysis of the products, upgrading process and maturation analyses.
References
APERC (Asia Pacific Energy Research Centre), 2006. APEC energy demand and supply outlook 2006, Tokyo, p. 1-92.
Beyssac O., Goffe B., Chopin C. and Rouzaud J.N., 2002. Raman spectra of carbonaceous material in metasediments: a new geothermometer, J. Meta- morphic Geol., 20, p. 859-871.
Directorate General for Mineral and Coal (DGMC)- MEMR, 2014. Indonesian Coal Resources. http:// www.minerba.esdm.go.id/public/38477/produksi- batubara/.produksi/.
Farmer, V.C., 1974. The lnfrared Spectra of Minerals. Mineralogical Society Monograph, London, 539 p.
Geological Agency (GA)-MEMR, 2012. Indonesian Balance of Fossil Energy Resources. http://psdg. bgl.esdm.go.id/index.php?option=com_content&v iew=article&id=1026&Itemid=641.
Ibarra, J.V., Muñoz, E. and Moliner, R, 1996. FTIR study of the evolution of coal structure during the coalifi- cation process. Org Geochem 24, p. 725-735.
Li, X., Hayashi, J-i., Li, C.Z., 2006. FT-Raman spec- troscopic study of the evolution of char structure during the pyrolysis of a Victorian brown coal, Fuel, 85, p. 1700-1707.
Manocha, S.M., 2003. Porous Carbon, Sadhana, 28; Parts 1 & 2, p. 335-348.
Mursito, A.T., Hirajima, T., Amelia, R., Simanjuntak, L. and Dewi, R., 2007. Investigation on Upgrading of Low Rank Coal by Water Steam Flows in the Ther- mal Environment. Proc. Annual Meeting (Spring) MMIJ 2007, II, p.37-38.
Mursito, A.T., Hirajima, T. and Sasaki, K., 2011. Alkaline hydrothermal de-ashing and desulfurization of low quality coal and its application to hydrogen-rich gas generation. Energy Conversion and Management 52, p. 762-769.
Painter, P,C., Snyder, R.W., Starsinic, M., Coleman, M.M., Kuehn, D.W. and Davis, A., 1981. Concern- ing the application of FT-IR to the study of coal: a critical assessment of band assignments and the application of spectral analysis programs. Appl Spectrosc 35, p. 475-485.
Quirico, E., Rouzaud, J.N., Bonal, L. and Montagnac, G., 2005. Maturation grade of coals as revealed by Raman spectroscopy: Progress and problems., Spectrochimica Acta Part A 61, p. 2368-2377.
Shimada, M., Iida, T., Kawarada, K., Chiba, Y., Mamoto, T. and Okayam, T., 2004. J Mater. Cycles. Waste Manag., 6, p.111-118.
Tuinstra, F. and Koenig, J. L., 1970. Raman spectrum of graphite. Journal of Chemical Physics, 53, p. 1126-1130.
Ulyanova, E.V., Molchanov, A.N., Prokhorov, I.Y. and Grinyov, V.G., 2014. Fine structure of Raman spec- tra in coals of different rank, International Journal of Coal Geology, 121, p. 37-43.
Van Doorn, J., Vuurman, M.A., Tromp, I., Stufkens, D.J. and Moulijn, J.A., 1990. Correlation between raman spectroscopic data and the temperature- programmed oxidation reactivity of coals and carbons, Fuel Processing Technology, 24, p. 407-413.
Velde, B. and Martinez, G., 1981. Effect of pressure on OH-stretching frequencies in kaolinite and ordered aluminous serpentine. Am Mineral 66, p. 196-200.
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