IMPLEMENTATION OF MATHEMATICAL EQUATION FOR CALCULATING ALUMINA EXTRACTION FROM BAUXITE TAILING DIGESTION
DOI:
https://doi.org/10.30556/imj.Vol19.No1.2016.363Keywords:
bauxite tailing, digestion, alumina extraction, mathematical model, Bayer processAbstract
Research on bauxite tailing digestion using pressurized batch reactor at a feed capacity of 86.66 kg had been conducted. Bauxite with -150 mesh of particle size is reacted with 42.15 kg of caustic soda (433.49 g/l) at 140oC for 1.0 to 2.5 hours using steam as heating media. Lime added are varied from 3 to 9 kg. After processing for a certain period of time, slurry product is transfered into a mixer. To evaluate percent extraction of Al2O3 from this process, the height of slurry level in the mixer, densities of the slurry, filtrat, and solid residue are measured and determined. The head sample of bauxite, filtrate and residue are analysed by using wet method to obtain Al2O3 content of each sample taken from the mixer. There are four equations that are used for obtaining the alumina extraction, namely : Vsl=4.176x+15.83 Wsl=(4.176x+15.83)ρsl S=(ρsl - ρl)/ (ρs - ρl) (ρs/ ρsl)*100% E=[10 (4.176x+15.83) [1- (ρsl - ρl)/ (ρs - ρl)]*[cl/FxF]% The calculation results show that by increasing lime added into the slurry, percent yield of alumina extraction tend to decrease from 46.63% for 3 kg of lime to 15.84% by using 9 kg of lime. Whereas by varying reaction time between 1.0-2.5 hours, percent yield of alumina extraction are fluctuation in the range of 42.07-60.54%, and the highest result was obtanined for 1,5 hours of reaction time. By implementing those four equations above for evaluating the data, we do not need to weigh the slurry in the reactor.References
Alcoa, 2016. Bauxite Interests, http://www.alcoa.com/alumina/en/info_page/bauxite_interests.asp, downloaded on May 9th, 2016.
Chen, H-L., Lewellyn, M., Chamberlain, O., Heitner, H., Kula, F., Dai, Q., Franz, C., 2007. Sodalite Scale Control In Alumina Bayer Process, Corrosion 2007, 11-15 March, Nashville, Tennessee.
Hond, R. D., Hiralal, I., Rijkeboer, A., 2007. Alumina yield in the bayer process past, present and prospects, The Minerals, Metals & Materials Society, The Netherlands, downloaded on May 9th, 2016.
Kontopoulos, A., Panias, D., and Paspaliaris, I., 1997. Precipitation of monohydrate alumina in the Bayer process I. National Technical University Of Athens Universite Libre De Bruxelles Hellenic Alumina Industry Contract JOE3-CT95- 0003. Publishable Final Report January 1996 to June 1997. Research funded in part by The European Commission in the framework of the Non Nuclear Energy Programme JOULE III.
Kopeliovich, D., 2012. Bayer process, http://www.substech.com/dokuwiki/doku. php?id=bayer_process, downloaded on May 9th, 2016.
Marsh, C., 2009. CFD modelling of alumina calciner furnaces. Seventh International Conference on CFD in the Minerals and Process Industries CSIRO. Melbourne. Australia 9-11 December 2009. E-mail address: cmarsh@engineeringCFD.com.
Oxana Fox, 2016. How to calculate percent solids by weight. http://www.ehow.com/how_7519269_cal culate-percent-solids-weight.html. downloaded on February 14th. 2016.
Palmer, Sara J. and Frost, Ray L. and Nguyen, Tai M. 2009. Hydrotalcites and their role in coordination of anions in Bayer liquors: Anion binding in layered double hydroxides. Coordination Chemistry Reviews 253(1-2):pp. 250-267. Copyright 2009 Elsevier.
Pan, X.L., Yu, H.Y. Dong, K.W., Tu. G.F., and Bi, S.W., 2012. Pre-desilication and digestion of gibbsitic bauxite with lime insodium aluminate liquor. International Journal of Minerals, Metallurgy, and Materials, vol. 19, issue 11, p. 973-977.
Reyner-Canham G., 1996. Descriptive Inorganic Chemistry, W.H. Freeman and Company, Second printing, ISBN C- 7167-2819-2, p. 213-216
Smith, P., 2009. The Processing Of High Silica Bauxites-Review Of Existing And Potential Processes. Hydrometallurgy, 98,162-176.
Tariq, M., Iqbal, M.M., Aziz, A., Shafiq, M., Sajid, M. and Mohammad, B., 2014. Recovery of alumina from Khushab bauxite by leaching with sulphuric acid and removal of iron impurity by ethanol, J.Chem.Soc.Pak., vol. 36, no. 4, p. 624-629.
The International Aluminium Institute, 2012. Aluminium for future generations, http://www.slideshare.net/cominst75/alu minium-for-future-generations, downloaded on May 9th, 2016.
Zhang, S. Du, H., Xu, H., Wang, S., Zhang, Y., 2009. Improved Ying precipitation of gibbsite from sodium aluminate solution by adding methanol. Hydrometallurgy 98 (2009) 38–44. journal homepage: www.elsevier.com/locate/.hydromet.
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